The Spanish champions beat city rivals Real Madrid in La Liga at the weekend and will look to go one better than last season in Europe. Last season's runners-up Atletico Madrid will begin their Champions League campaign on a high after defeating Real Madrid on Saturday.
The Bayern Munich star provided for his country once more during the victory over Scotland and must be considered Joachim Low's top attacking option.The dust has settled on Germany's big night in Rio and Joachim Low's rebuilding job is well under way.
The England goalkeeper saved two penalties following goals for Stevan Jovetic and Aleksandar Kolarov in normal time, with Dimitris Diomantakos scoring twice.
The England international produced a neat finish just five minutes in after pouncing on a deflected effort from Daniel Sturridge.
The Serie A outfit struggled without their enigmatic striker in their first competitive match under their new coach.
The veteran striker broke Ronaldo's record for finals goals as Thomas Muller, Sami Khedira, Toni Kroos and Andre Schurrle combined to decimate Luiz Felipe Scolari's side.